Thermodynamic Properties of Fluids from Fluctuation Solution Theory
Author | : |
Publisher | : |
Total Pages | : 23 |
Release | : 1990 |
ISBN-10 | : OCLC:727233469 |
ISBN-13 | : |
Rating | : 4/5 ( Downloads) |
Download or read book Thermodynamic Properties of Fluids from Fluctuation Solution Theory written by and published by . This book was released on 1990 with total page 23 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluctuation Theory develops exact relations between integrals of molecular correlation functions and concentration derivatives of pressure and chemical potential. These quantities can be usefully correlated, particularly for mechanical and thermal properties of pure and mixed dense fluids and for activities of strongly nonideal liquid solutions. The expressions yield unique formulae for the desirable thermodynamic properties of activity and density. The molecular theory origins of the flucuation properties, their behavior for systems of technical interest and some of their successful correlations will be described. Suggestions for fruitful directions will be suggested.